11.5 Two ideal gas thermometers A and B use oxygen and hydrogen respectively. The following observations are made :
Temperature Pressure thermometer A Pressure thermometer B |
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Triple-point of water |
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Normal melting point of |
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(a) What is the absolute temperature of normal melting point of sulphur as read by thermometers A and B?
(b) What do you think is the reason behind the slight difference in answers of thermometers A and B? (The thermometers are not faulty). What further procedure is needed in the experiment to reduce the discrepancy between the two readings?
Let the normal melting point of sulphur =
At this temperature, pressure in thermometer A, = 1.797 × 10 Pa
According to Charles’ law,
= 392.69 K
Therefore, the absolute temperature of the normal melting point of sulphur as read by thermometer A is 392.69 K.
At triple point 273.16 K, the pressure in thermometer B, P = 0.200 × 10 Pa
At temperature , the pressure in thermometer B, P = 0.287 × 10 Pa
According to Charles’ law,
Therefore, the absolute temperature of the normal melting point of sulphur as read by thermometer B is 391.98 K.
The oxygen and hydrogen gas present in thermometers A and B respectively are not perfect ideal gases. Hence, there is a slight difference between the readings of thermometers A and B.
To reduce the discrepancy between the two readings, the experiment should be carried under low-pressure conditions. At low pressure, these gases behave as perfect ideal gases.
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