The activity R of an unknown radioactive nuclide is measured at hourly intervals. The result found are tabulated as follows:

t(h)

0

1

2

3

4

R(MBq)

100

35.36

12.51

4.42

1.56

(i) Plot the graph of R versus t and calculate half-life from the graph.

(ii) Plot the graph of lnRR0 versus t and obtain the value of half-life from the graph.

Hint: The decay rate depends on the active nuclei.
Step 1: Find the value of lnRR0.
In the table given below, we have listed values of R(MBq) and lnRR0.

t(h)

0

1

2

3

4

R(MBq)

100

35.36

12.51

4.42

1.56

lnRR0

-

-1.04

-2.08

-3.11

-4.16

Step 2: Draw the graph between R and t.

(i) When we plot the graph of R versus t, we obtain an exponential curve as shown.

From the graph, we can say that activity R reduces to 50% in t = OB 40 min

So, t1/240 min.

Step 3: Draw the graph between lnRR0 and t.

(ii) The adjacent figure shows the graph of lnRR0 versus t.

The slope of this graph=-λ

From the graph, λ=-(-4.16-3.111)=1.05h-1

Half-life, T1/2=0.693λ=0.6931.05=0.66h=39.6 min40 min